Biologically-Inspired Radiation-Reflecting Ablator

materials and coatings
Biologically-Inspired Radiation-Reflecting Ablator (TOP2-261)
An alternative approach to forming radiation-reflecting materials
Overview
Radiative heating during reentry becomes very significant as vehicles get larger and enter at high speeds. The specifics of the radiation depend upon vehicle characteristics, speed, and the atmosphere. Radiative heating occurs very early during reentry and at specific wavelengths, dependent upon the atmosphere. Thermal protection systems capable of dealing with such heat fluxes can be very heavy. An alternative is to make a heat shield that can reflect the radiation. One approach to radiation reflection is through photonic effects which is time consuming and expensive. Ames Research Center has developed an alternative approach to forming radiation-reflecting materials by using the ordered structures that are found in nature to make materials that can be used to reflect radiation called Biologically-Inspired Radiation-Reflecting Ablator (BIRRA).

The Technology
Reentry heating comes from two primary sources: Convective heating from both the flow of hot gas past the surface of the vehicle and catalytic chemical recombination reactions at the surface; and Radiation heating from the energetic shock layer in front of the vehicle. The magnitude of stagnation heating is dependent on a variety of parameters, including reentry speed, vehicle effective radius, and atmospheric density. As reentry speed increases, both convective and radiation heating increase. At high speeds, radiation heating can quickly dominate and as the effective vehicle radius increases, convective heating decreases, but radiation heating increases. Radiation during reentry is a function of reentry speed which occurs very early in reentry for very specific wave-lengths and is dependent upon atmospheric composition. The Biologically-Inspired Radiation-Reflecting Ablator (BIRRA) approach converts amorphous silica of diatoms to a more refractory material, Silicon carbide (SiC), and incorporates it into a Thermal Protection System (TPS), especially near the surface to provide enhanced reflection during the initial stage of reentry into planetary atmospheres at high speeds. Different diatom species reflect different wavelengths. This conversion is performed in a fluidized bed reactor or other type of reactor to convert naturally ordered structures to higher temperature materials with a photonic structure that can better reflect radiation. TPS that shields vehicles from both radiative and convective heat would allow reduction of the mass fraction of the TPS, which will increase the mass fraction available for payload or reduce the overall mass and thus launch and propulsion requirements.
Computer graphic rendering of a star diatom The technology  is incorporated  into a Thermal Protection System (TPS), especially near the surface to provide enhanced reflection during the initial stage of reentry into planetary atmospheres at high speeds.
Benefits
  • Photonic structures can be computationally designed and synthetically fabricated
  • Photonic effects can be used to reflect radiation
  • Radiative reflector can conserve mass that will decrease propulsion costs and/or increase payload capacity
  • Decreased total weight of ablation shield

Applications
  • Aerospace and Defense
  • Coating Industry
  • Thermal Protection Systems
Technology Details

materials and coatings
TOP2-261
ARC-16956-1
9,908,642
Similar Results
An artist’s rendition of the Parker Solar Probe approaching the Sun
Cryogenic Selective Surfaces
These materials, which are composed of highly optically transmissive materials, are engineered to provide near-perfect reflection of the full solar spectrum in space. The materials are finely divided such that they scatter and reflect the incoming radiation from the UV down into the mid-IR and are also coated in some fashion with silver to extend the reflectance down into the far IR region of the solar spectrum. With this near-perfect reflectance of the complete solar spectrum, the scientists envision use of these materials for maintaining cryogenic temperatures for extended periods of time in space. The materials have also been developed into highly flexible, moisture resistant selective surface paint.The use and storage of cryogenics fluids is critical to many space operations, and while there are thermal control coatings in use today for spacecraft, none can provide this near-perfect reflection required for long-term maintenance of cryogenic temperatures.
Computer-implemented energy depletion radiation shielding
The difference between Layered Energy Depletion Radiation Shielding (LEDRS) and Stacked Energy Depletion Radiation Shielding (SEDRS) is how the piece of matter, or shield, is analyzed as radiation passes through the matter. SEDRS involves using a defined and ordered stack of layers of shielding with different material properties such that the thickness and chemical properties of each material maximizes the absorption of energy from the radiation particles that are most damaging to the target. The SEDRS shielding method aims to provide the maximum level of energy absorption while still keeping shielding mass and volume low. The process of LEDRS involves using layers of shielding material such that the thickness of each material is designed to absorb the maximum amount of energy from the radiation particles that are most damaging to the target after subsequent layers of shielding. The more energy is absorbed by the shielding material, the less energy will be deposited in the target minimizing the required mass to achieve a resulting lower dose for a given geometrical feature. The LEDRS shielding method aims to provide the maximum level of energy absorption. The process for designing LEDRS views potential radiation shields as a cascade of effects from each shielding layer to the next and is helpful for investigating the particular effects of each layer. SEDRS and LEDRS can improve any technology that relies on the controlled manipulation of a radiation field by interaction with a material element.
Woven Thermal Protection System
Going farther, faster and hotter in space means innovating how NASA constructs the materials used for heat shields. For HEEET, this results in the use of dual-layer, three-dimensional, woven materials capable of reducing entry loads and lowering the mass of heat shields by up to 40%. The outer layer, exposed to a harsh environment during atmospheric entry, consists of a fine, dense weave using carbon yarns. The inner layer is a low-density, thermally insulating weave consisting of a special yarn that blends together carbon and flame-resistant phenolic materials. Heat shield designers can adjust the thickness of the inner layer to keep temperatures low enough to protect against the extreme heat of entering an atmosphere, allowing the heat shield to be bonded onto the structure of the spacecraft itself. The outer and inner layers are woven together in three dimensions, mechanically interlocking them so they cannot come apart. To create this material, manufacturers employ a 3-D weaving process that is similar to that used to weave a 2-D cloth or a rug. For HEEET, computer-controlled looms precisely place the yarns to make this kind of complex three-dimensional weave possible. The materials are woven into flat panels that are formed to fit the shape of the capsule forebody. Then the panels are infused with a low-density version of phenolic material that holds the yarns together and fills the space between them in the weave, resulting in a sturdy final structure. As the size of each finished piece of HEEET material is limited by the size of the loom used to weave the material, the HEEET heat shield is made out of a series of tiles. At the points where each tile connects, the gaps are filled through inventive designs to bond the tiles together.
Entry-descent
A New Family of Low-Density, Flexible Ablators
The invention provides a family of low density, flexible ablators comprising of a flexible fibrous substrate and a polymer resin. The flexible ablators can withstand a wide range of heating rates (40-540 Watts/cm2) with the upper limit of survivable heat flux being comparable to the survivable heat flux for rigid ablators, such as PICA and Avcoat. The amount and composition of polymer resin can be readily tailored to specific mission requirements. The material can be manufactured via a monolithic approach using versatile manufacturing methods to produce large area heat shields, which provides a material with fewer seams or gaps. The goals of the work are primarily twofold: (i) to develop flexible, ablative Thermal Protection System (TPS) material on a large, blunt shape body which provides aerodynamic drag during hypervelocity atmospheric entry or re-entry, without perishing from heating by the bow shock wave that envelopes the body; and (ii) to provide a relatively inexpensive TPS material that can be bonded to a substrate, that is unaffected by deflections, by differences in thermal expansion or by contraction of a TPS shield, and that is suitable for windward and leeward surfaces of conventional robotic and human entry vehicles that would otherwise employ a rigid TPS shield. This technology produces large areas of heat shields that can be relatively easily attached on the exterior of spacecraft.
Eruopa
Atomic Number (Z)-Grade Radiation Shields from Fiber Metal Laminates
This technology is a flexible, lighter weight radiation shield made from hybrid carbon/metal fabric and based on the Z-grading method of layering metal materials of differing atomic numbers to provide radiation protection for protons, electrons, and x-rays. To create this material, a high density metal is plasma spray-coated to carbon fiber. Another metal with less density is then plasma spray-coated, followed by another, and so on, until the material with the appropriate shielding properties is formed. Resins can be added to the material to provide structural adhesion, reducing the need for mechanical bonding. This material is amenable to molding and could be used to build custom radiation shielding to protect cabling and electronics in situations where traditional metal shielding is difficult to place.
Stay up to date, follow NASA's Technology Transfer Program on:
facebook twitter linkedin youtube
Facebook Logo Twitter Logo Linkedin Logo Youtube Logo