Aerofoam

The approach in developing the LCX system was to provide a combination of advantages in thermal performance, structural capability, and operations. The system is particularly suited for the complex piping, tanks, and apparatus subjected to the ambient environment common in the aerospace industry. The low-cost approach also lends the same technology to industrial applications such as building construction and chilled-water piping. The system can increase reliability and reduce life cycle costs by mitigating moisture intrusion and preventing the resulting corrosion that plagues subambient-temperature insulation systems operating in the ambient (humidity and rain) environment. Accumulated internal water is allowed to drain and release naturally over the systems normal thermal cycles. The thermal insulation system has a long life expectancy because all layer materials are hydrophobic or otherwise waterproof. LCX systems do not need to be perfectly sealed to handle rain, moisture accumulation, or condensation. Mechanically, the LCX system not only withstands impact, vibration, and the stresses of thermal expansion and contraction, but can help support pipes and other structures, all while maintaining its thermal insulation effectiveness. Conventional insulation systems are notoriously difficult to manage around pipe supports because of the cracking and damage that can occur. Used alone or inside another structure or panel, the LCX layering approach can be tailored to provide additional acoustic or vibration damping as a dual function with the thermal insulating benefits. Because LCX systems do not require complete sealing from the weather, it costs less to install. The materials are generally removable, reusable, and recyclable, a feature not possible with other insulation systems. This feature allows removable insulation covers for valves, flanges, and other components (invaluable benefits for servicing or inspection) to be part of original designs. Thermal performance of the LCX system has been shown to equal or exceed that of the best polyurethane foam systems, which can degrade significantly during the first two years of operation. With its inherent springiness, the system allows for simpler installation and, more importantly, better thermal insulation because of its consistency and full contact with the cold surface. Improved contact with the cold surface and better closure of gaps and seams are the keys to superior thermal performance in real systems. Eliminating the requirement for glues, sealants, mastics, expansion joints, and vapor barriers provides dramatic savings in material and labor costs of the installed system.

Researchers at NASA's Glenn Research Center have developed an approach to significantly improve the mechanical properties and durability of aerogels without adversely affecting their desirable properties. This approach involves coating conformally and cross-linking the individual skeletal aerogel nanoparticles with engineering polymers such as isocyanates, epoxies, polyimides, and polystyrene. The mechanism of cross-linking has been carefully investigated and is made possible by two reactions: a reaction between the cross-linker and the surface of the aerogel framework and a reaction propagated by the cross-linker with itself. By tailoring the aerogel surface chemistry, Glenn's approach accommodates a variety of different polymer cross-linkers, including isocyanates, acrylates, epoxies, polyimides, and polystyreneenabling customization for specific mission requirements. For example, polystyrene cross-linked aerogels are extremely hydrophobic, while polyimide versions can be used at higher temperatures. Recent work has led to the development of strong aerogels with better elastic properties, maintaining their shape even after repeated compression cycling. By tailoring the internal structure of the silica gels in combination with a polymer conformal coating, the aerogels may be dried at the ambient condition without supercritical fluid extraction.

The AERoBOND and AERoBOND+ technologies are composite resin materials design innovations that enable new methods for composites joining and manufacturing. The resins are formulated with carefully selected off-set stoichiometries to delay/control the cure such that initial curing of individual components can be followed separately by joining/curing of components together. The ability to delay and control the co-cure joining step provides ease of manufacturing of multi-part composite structures, without compromising joint integrity. There are significant cost savings associated with eliminating fasteners and joint surface preparation steps. To date, the focus of the NASA development effort has been on novel epoxy-based prepreg formulations though other types of thermosets could be considered as well. The AERoBOND+ innovation provides an added adhesive layer to the AERoBOND joint design to improve the ability to join composite surfaces when these surfaces are less tightly matched. Conventional adhesives, e.g., film, paste, etc., are employed. By including an adhesive between the offset stoichiometric prepreg plies, the adhesive can fill the gaps between the bonding surfaces while maintaining reflowable AERoBOND layer interfaces. Since all interfaces are reflowable, they are much more tolerant of surface contamination, thereby mitigating a primary challenge for conventional adhesive bonding.

This technology (AERoBOND) enables the assembly of large-scale, complex composite structures while maintaining predictable mechanical and material properties. It does so by using a novel barrier-ply technology consisting of an epoxy resin/prepreg material with optimal efficiency, reliability, and performance. The barrier-ply materials prevent excessive mixing between conventional composite precursors and stoichiometrically-offset epoxy precursors during the cure process by forming a gel early in the cure cycle before extensive mixing can occur. The barrier ply is placed between the conventional laminate preform and the stoichiometrically-offset ply or plies placed on the preform surface, thus preventing excessive mass transfer between the three layers during the cure process. In practice, the barrier ply could be combined with the offset ply to be applied as a single, multifunctional surfacing layer enabling unitized assembly of large and complex structures. The AERoBOND method is up to 40% faster than state-of-the-art composite manufacturing methods, allows for large-scale processing of complex structures, eliminates the potential for weak bond failure modes, and produces composites with comparable mechanical properties as compared with those prepared by co-cure.

There has been much interest in developing polymeric nanocomposites with ultrahigh thermal conductivities, such as with exfoliated graphite or with carbon nanotubes. These materials exhibit thermal conductivity of 3,000 W/mK measured experimentally and up to 6,600 W/mK predicted from theoretical calculations. However, when added to polymers, the expected thermal conductivity enhancement is not realized due to poor interfacial thermal transfer. This technology is a method of forming carbon-based fillers to be incorporated into highly thermal conductive nanocomposite materials. Formation methods include treatment of an expanded graphite with an alcohol/water mixture followed by further exfoliation of the graphite to form extremely thin carbon nanosheets that are on the order of between about 2 and about 10 nanometers in thickness. The carbon nanosheets can be functionalized and incorporated as fillers in polymer nanocomposites with extremely high thermal conductivities.