Optical concentration sensor for liquid solution

This technology was developed to improve Armstrong's multi-patented FOSS system, which has long been used to measure temperature and liquid levels in cryogenic environments. When the sensing system's fibers trapped humidity from the surrounding environment before their submersion into cryogenic liquids, the moisture adversely affected outputs. A new manufacturing process solves this problem, increasing reliability and accuracy not only of NASA's FOSS but also any fiber optic sensing system. How It Works Armstrong has developed a two-step process to assemble the sensors. First, the bare sensor fiber is inserted into an oven to expel all moisture from the fiber coating. Then, the moisture-free fiber is placed inside a humidity-controlled glove box to prevent it from absorbing any new moisture. While inside the glove box, the fiber is inserted into a loose barrier tubing that isolates the fiber yet is still thin enough to provide adequate thermal transfer. The tubing can be further purged with various gases while it is inside the glove box to provide additional moisture isolation. This innovation is particularly useful for fiber optic systems that measure temperature and that identify any temperature stratifications within cryogenic liquids. Why It Is Better This process seals sensor fibers from environmental moisture, enabling fiber optic sensing systems to operate reliably in humid environments. The innovation eliminates erroneous readings that can occur due to moisture collection on the fiber sensors. For more information about the full portfolio of FOSS technologies, see DRC-TOPS-37 or visit https://technology-afrc.ndc.nasa.gov/featurestory/fiber-optic-sensing

This invention is a system and associated method that is a two step process. It provides a contaminant treatment pouch, referred to as a urine cell or contaminant cell that converts urine or another liquid containing contaminants into a fortified drink, engineered to meet human hydration, electrolyte and caloric requirements. It uses a variant of forward osmosis (FO) to draw water from a urine container into the concentrated fortified drink as part of a recycling stage. An activated carbon pretreatment removes most organic molecules. Salinity of the initial liquid mix (urine plus other) is synergistically used to enhance the precipitation of organic molecules so that activated carbon can remove most of the organics. A functional osmotic bag is then used to remove inorganic contaminants. If a contaminant is processed for which the saline content is different than optimal for precipitating organic molecules, the saline content of the liquid should be adjusted toward the optimal value for that contaminant.

The pre-treatment solution increases the solubility of calcium in urine brines by reducing the concentration of sulfates. When the solution is properly dosed, it enables biological, physical, and chemical stabilization of flushed urine for storage and distillation up to a steady 87% water recovery, as realized aboard the U.S. segment of the ISS, without precipitation of minerals such as gypsum. Turning wastewater or seawater into potable water requires three important steps shared by the UPA and Water Recovery System (WRS) aboard the ISS: 1) pre-treatment, 2) distillation or membrane filtration, and 3) transport and storage of potable water and brine. Added during the first step, the pre-treatment solution improves the efficiency of the UPA by reducing the formation of solid precipitates caused by urinary calcium, sulfate ions, and sulfuric acid. This reduction in-turn creates less acidic brines which means more water can be recovered along with less surface scaling and clogging, further increasing recovery. As an added benefit, the solution contains a biocide that prevents the growth of bacteria and fungus, thereby increasing storage time of the treated urine. Although the pre-treatment solution was developed for the ISSs UPA , the technology can potentially be used on Earth to pretreat contaminated water from organic-laden, high-salinity wastewaters. Adding the solution is a simple process that can be scaled to fit demand. It has the potential to improve water recovery in many applications such as: desalination plants, brackish water treatment, mining water treatment, hydraulic fracturing operations, and more. The pre-treatment solution may also lend itself for use in the transport and storage of wastewater due to the solution's ability to prevent microbial growth.

NASAs novel ceramic dielectric material enables extremely high-sensitivity humidity sensing. The ceramic sensing element is robust, can be manufactured using printing processes, and exhibits fast response and recovery speeds with large capacitance and resistance response/change per relative humidity unit change across a wide range of humidity levels in a log-linear response. Preliminary test data conducted in a humidity test chamber show a log-linear measured response in capacitance from 5 nanofarads (at 30% relative humidity, room temperature) to 0.2 millifarads (at 90% relative humidity, room temperature). The inventors discovered the humidity sensing element technology during their efforts to develop next-generation energy storage materials and devices for NASA. The inventors were initially puzzled by large swings in capacitance observed over the course of any given day in one particular dielectric composition, and, ultimately, they were able to trace these unexpected changes in capacitance back to corresponding changes in ambient humidity, even those occurring from breathing and exhalation. The sensor element can be formed using a dielectric ink or paste formulation, also developed by NASA, via traditional screen printing or advanced ink jet, aerosol, or 3D printing methods. The printed sensor element can be very thin, on the order of microns in thickness, with a small footprint, one square centimeter or less.

Armstrong has developed a robust fiber optic–based sensing technology that offers extraordinary accuracy in liquid level measurements. The sensing system uses fiber optic Bragg sensors located along a single fiber optic cable. These sensors actively discern between the liquid and gas states along a continuous fiber and can accurately pinpoint the liquid level. How It Works The technology uses a resistive heater wire bundled with the optical fiber. The heater is pulsed to induce a local temperature change along the fiber, and the fiber Bragg grating data is used to monitor the subsequent cooling of the fiber. The length of fiber in the liquid cools more rapidly than the portion of the fiber in the gas above the liquid. The measurement system accurately establishes the location of this transition to within 1/4-inch. Why It Is Better Armstrong's liquid level sensing technology was originally developed to measure cryogenic liquid levels in rockets, and it represents a significant advancement in the state of the art in this application. Conventional methods for measuring cryogenic liquid levels rely on cryogenic diodes strategically placed along a rod or rack. The diodes are mounted in pre-selected, relatively widely spaced positions along the length of a rod; this configuration provides limited, imprecise data. Furthermore, each diode on the rod has two wires associated with it, which means a single system may require a large number of wires, making installation, connectivity, and instrumentation cumbersome. Armstrong's novel technology provides liquid measurements with much greater precision, achieving measurements at 1/4-inch intervals. Furthermore, the streamlined system uses just two wires, which greatly simplifies installation and instrumentation. Due to its extraordinary accuracy and ease of use, Armstrong's measurement system offers important advantages for a wide range of applications beyond cryogenic liquids. In Addition Researchers have developed a new manufacturing process that improves the ability of fiber optic sensing systems to measure temperature and liquid levels when operating in humid environments. The process involves eliminating moisture from the optical fiber coating, then completing the sensor assembly within humidity-controlled conditions. The resulting sensor hardware provides precise and accurate measurements even when operating in a humid environment. For more information about the full portfolio of FOSS technologies, see DRC-TOPS-37 or visit https://technology-afrc.ndc.nasa.gov/featurestory/fiber-optic-sensing