Composite Dielectric Inks for Humidity Sensing

NASAs novel ceramic dielectric material enables extremely high-sensitivity humidity sensing. The ceramic sensing element is robust, can be manufactured using printing processes, and exhibits fast response and recovery speeds with large capacitance and resistance response/change per relative humidity unit change across a wide range of humidity levels in a log-linear response. Preliminary test data conducted in a humidity test chamber show a log-linear measured response in capacitance from 5 nanofarads (at 30% relative humidity, room temperature) to 0.2 millifarads (at 90% relative humidity, room temperature). The inventors discovered the humidity sensing element technology during their efforts to develop next-generation energy storage materials and devices for NASA. The inventors were initially puzzled by large swings in capacitance observed over the course of any given day in one particular dielectric composition, and, ultimately, they were able to trace these unexpected changes in capacitance back to corresponding changes in ambient humidity, even those occurring from breathing and exhalation. The sensor element can be formed using a dielectric ink or paste formulation, also developed by NASA, via traditional screen printing or advanced ink jet, aerosol, or 3D printing methods. The printed sensor element can be very thin, on the order of microns in thickness, with a small footprint, one square centimeter or less.

A resistor-type sensor was fabricated which has a network of cross-linked SWCNTs with purity over 99%. An ordinary cellulose paper used for filtration was employed as the substrate. The filter paper exhibits medium porosity with a flow rate of 60 mL/min and particle retention of 5-10m. The roughness and porosity of the papers are attractive because they increase the contact area with the ambient air and promote the adhesion to carbon nanotubes. The SWCNTs were functionalized with carboxylic acid (COOH) to render them hydrophilic, thus increasing the adhesion with the substrate. The functionalized SWCNTs were dispersed in dimethylformamide solution. The film composed of networks of cross-linked CNTs was formed using drop-cast coating followed by evaporation of the solvent. Adhesive copper foil tape was used for contact electrodes. Our sensors outperformed the oxide nanowire-based humidity sensors in terms of sensitivity and response/recovery times.

This technology was developed to improve Armstrong's multi-patented FOSS system, which has long been used to measure temperature and liquid levels in cryogenic environments. When the sensing system's fibers trapped humidity from the surrounding environment before their submersion into cryogenic liquids, the moisture adversely affected outputs. A new manufacturing process solves this problem, increasing reliability and accuracy not only of NASA's FOSS but also any fiber optic sensing system. How It Works Armstrong has developed a two-step process to assemble the sensors. First, the bare sensor fiber is inserted into an oven to expel all moisture from the fiber coating. Then, the moisture-free fiber is placed inside a humidity-controlled glove box to prevent it from absorbing any new moisture. While inside the glove box, the fiber is inserted into a loose barrier tubing that isolates the fiber yet is still thin enough to provide adequate thermal transfer. The tubing can be further purged with various gases while it is inside the glove box to provide additional moisture isolation. This innovation is particularly useful for fiber optic systems that measure temperature and that identify any temperature stratifications within cryogenic liquids. Why It Is Better This process seals sensor fibers from environmental moisture, enabling fiber optic sensing systems to operate reliably in humid environments. The innovation eliminates erroneous readings that can occur due to moisture collection on the fiber sensors. For more information about the full portfolio of FOSS technologies, see DRC-TOPS-37 or visit https://technology-afrc.ndc.nasa.gov/featurestory/fiber-optic-sensing

Many researchers have attempted to use polymer-ceramic composites to improve the thermal and dielectric performance of polymer insulation for high voltage, high temperature electronics. However, using composite materials has been challenging due to manufacturing issues like incomplete mixing, inhomogeneous properties, and void formation. Here, NASA has developed a method of preparing and extruding polymer-ceramic composites that results in high-quality, flexible composite ribbons. To achieve this, pellets of a thermoplastic (e.g., polyphenylsulfone or PPSU) are coated with an additive then mixed with particles of a ceramic (e.g., boron nitride or BN) as shown in the image below. After mixing the coated polymer with the ceramic particles, the blended material was processed into ribbons or films by twin-screw extrusion. The resulting ribbons are highly flexible, well-mixed, and void free, enabled by the coated additive and by using a particle mixture of micronized BN and nanoparticles of hexagonal BN (hBN). The polymer-ceramic composite showed tunable dielectric and thermal properties depending on the exact processing method and composite makeup. Compared to the base polymer material, the composite ribbons showed comparable or improved dielectric properties and enhanced thermal conductivity, allowing the composite to be used as electrical insulation in high-power, high-temperature conditions. The related patent is now available to license. Please note that NASA does not manufacturer products itself for commercial sale.

There has been much interest in developing polymeric nanocomposites with ultrahigh thermal conductivities, such as with exfoliated graphite or with carbon nanotubes. These materials exhibit thermal conductivity of 3,000 W/mK measured experimentally and up to 6,600 W/mK predicted from theoretical calculations. However, when added to polymers, the expected thermal conductivity enhancement is not realized due to poor interfacial thermal transfer. This technology is a method of forming carbon-based fillers to be incorporated into highly thermal conductive nanocomposite materials. Formation methods include treatment of an expanded graphite with an alcohol/water mixture followed by further exfoliation of the graphite to form extremely thin carbon nanosheets that are on the order of between about 2 and about 10 nanometers in thickness. The carbon nanosheets can be functionalized and incorporated as fillers in polymer nanocomposites with extremely high thermal conductivities.