Advanced Supercritical Water Oxidation Reactor

The low-temperature oxidation catalyst technology employs a novel catalyst formulation, termed platinized tin oxide (Pt/SnOx). The catalysts can be used on silica gel and cordierite catalyst supports, and the latest developments provide sprayable formulations for use on a range of support types and shapes. Originally developed for removal of CO, the catalyst has also proven effective for removal of formaldehyde and other lightweight hydrocarbons. NASA researchers have also extended the capability to include reduction of NOx as well as developed advanced chemistries that stabilized the catalyst for automotive catalytic converters via the engineered addition of other functional components. These catalyst formulations operate at elevated temperatures and have performed above the EPA exhaust standards for well beyond 25,000 miles. In addition, the catalyst can be used in diesel engines because of its ability to operate over an increased temperature range. For use as a gas sensor, the technology takes advantage of the exothermic nature of the catalytic reaction to detect formaldehyde, CO, or hydrocarbons, with the heat being produced proportional to the amount of analyte present.

In one of NASA Glenn's innovations, a shaped recess can be formed on a surface associated with fluid flow. Often V-shaped, this shaped recess can be configured to create or induce fluid effects, temperature effects, or shedding effects. For example, the shaped recess can be paired (upstream or downstream) with a cooling channel. The configuration of the shaped recess can mitigate the lift-off or separation of the cooling jets that are produced by the cooling channels, thus keeping the cooling jets trained on turbine blades and enhancing the effectiveness of the film-cooling process. The second innovation produced to improve film cooling addresses problems that occur when high-blowing ratios, such as those that occur during transient operation, threaten to diminish cooling effectiveness by creating jet detachment. To keep the cooling jet attached to the turbine blade, and also to spread the jet in the spanwise direction, NASA Glenn inventors have successfully used cooling holes that reduce loss by blowing in the upstream direction. In addition, fences may be used upstream of the holes to bend the cooling flow back toward the downstream direction to further reduce mixing losses. These two innovations represent a significant leap forward in making film cooling for turbine blades, and therefore the operation of turbine engines, more efficient.

NASA's Liquid Sorbent Carbon Dioxide Removal System was designed as an alternative to the current CO2 removal technology used on the International Space Station (ISS), which uses solid zeolite media that is prone to dusting, has a low absorption capacity, and requires high regeneration temperatures and frequent maintenance. Motivated by CO2 removal systems on submarines, NASA innovators began investigating the use of liquid sorbents. Liquid sorbents have a capacity four times greater than solid zeolites, require low regeneration temperature, and need fewer unreliable moving mechanical parts than solid based systems. While submarine CO2 scrubbers spray an adsorbing chemical directly into the air stream and allow the liquid to settle, NASA's new system uses a capillary driven 3D printed microchannel direct air/liquid contactor in a closed loop system. The Liquid Sorbent Carbon Dioxide Removal System is robust and reliable, while being low in weight, volume, and power requirements. The system is capable of reaching equilibrium when the liquid sorbent surface is being regenerated at a rate equal to the rate of absorption into the liquid.

Storage and transfer of fluid commodities such as oxygen, hydrogen, natural gas, nitrogen, argon, etc. is an absolute necessity in virtually every industry on Earth. These fluids are typically contained in one of two ways; as low pressure, cryogenic liquids, or as a high pressure gases. Energy storage is not useful unless the energy can be practically obtained ("un-stored") as needed. Here the goal is to store as many fluid molecules as possible in the smallest, lightest weight volume possible; and to supply ("un-store") those molecules on demand as needed in the end-use application. The CFC concept addresses this dual storage/usage problem with an elegant charging/discharging design approach. The CFC's packaging is ingeniously designed, tightly packing aerogel composite materials within a container allows for a greater amount of storage media to be packed densely and strategically. An integrated conductive membrane also acts as a highly effective heat exchanger that easily distributes heat through the entire container to discharge the CFC quickly, it can also be interfaced to a cooling source for convenient system charging; this feature also allows the fluid to easily saturate the container for fast charging. Additionally, the unit can be charged either with cryogenic liquid or from an ambient temperature gas supply, depending on the desired manner of refrigeration. Finally, the heater integration system offers two promising methods, both of which have been fabricated and tested, to evenly distribute heat throughout the entire core, both axially and radially. NASA engineers also applied the CFC to a Cryogenic Oxygen Storage Module to store oxygen in solid-state form and deliver it as a gas to an end-use environmental control and/or life support system. The Module can scrub out nuisance or containment gases such as carbon dioxide and/or water vapor in conjunction with supplying oxygen, forming a synergistic system when used in a closed-loop application. The combination of these capabilities to work simultaneously may allow for reduced system volume, mass, complexity, and cost of a breathing device.

Both oscillators are flow control devices based on novel geometric designs. They have no moving parts and produce spatially oscillating jets. Each was designed to address a particular limitation of current oscillators. Gaining control authority by decoupling frequency and amplitude: Existing oscillators are limited in that the frequency of oscillation is controlled by input pressure or mass flow rate--the frequency and amplitude (mass flow rate) are coupled, limiting control authority over the oscillators. The new oscillator design decouples the frequency from the amplitude by employing a novel design featuring a main oscillator that controls the amplitude and a small oscillator that controls the frequency of the oscillations (see Figure 1). The decoupled oscillator delivers high (or low) mass flow rates without changing the frequency and vice versa. Gaining control authority by synchronizing the entire oscillator jet array: Existing oscillators in an array oscillate randomly. While this is useful for mixing enhancement, synchronized flow may be more beneficial for active flow control applications. The simple design of the new Langley synchronized oscillator achieves synchronization without having electro/mechanical or any other moving parts. The new oscillator enables synchronization of an entire array by properly designing the feedback loops to have one unique feedback signal to each actuator. Once each actuator has the same feedback signal, each main jet attaches to one side of the Coanda surface at the same time, allowing synchronized oscillation, as shown in Figure 2.