Solar Cell Health Monitoring

Conventional scintillation radiation detectors make use of materials that emit light when hit by ionizing radiation. These large, bulky scintillators range anywhere from 6 inches to 6 feet in size. They are attached to glass photomultiplier tubes (PMTs), which are fragile, require high voltages, and are extremely sensitive to temperature changes. Conventional detectors also include a wave shifter (a material with a dopant to re-emit the scintillator light to match the sensitivity of the PMT or photodiode) which reduces efficiency and introduces unwanted weight and bulk. Glenn's particle counter overcomes these challenges. A prototype was constructed from off-the-shelf components, and features a small scintillator (less than six inches long) and a low-voltage, UV-sensitive, wide-bandgap photodiode as the detector. Careful matching of the properties of the light emitted from the scintillator, and tailoring the sensitivity of the photodiode eliminates the need for a PMT and a wave shifter, not only saving space, weight, and power but also eliminating potential failure modes. By using wide-bandgap detectors, it can operate in changing temperature, vibration, pressure, and gravity conditions without need for a temperature compensation system. Built from solid-state components, Glenn's device is compact and robust.

Conventional ambient-temperature oxygen sensors are limited in various ways: optically based sensors can be expensive and challenging to manufacture; electrochemical cells with liquid electrolytes can have limited lifetimes and become leak sources; and both types of sensors are difficult to miniaturize. These problems are addressed with Glenn's novel ambient temperature oxygen microsensor, which is based on a Nafiontm polymer electrolyte, microfabricated using thin-film technologies. In the past, one drawback of Nafiontm film has been that it can lose conductivity when the moisture content in the film is too low, potentially affecting sensor operation. Glenn researchers devised a method to use certain salts to hold water molecules in the Nafiontm film structure at room temperature. The presence of these salts provides extra sites in the film to promote proton (H+) mobility, thus improving film conductivity and overall sensor performance, particularly in arid and high-temperature environments. The innovative use of metal/metal oxide as the reference electrode enables miniaturization by eliminating the reference gas and sealing the reference electrode. The combination of interdigitized electrodes with the unique metal/metal oxide reference electrode permits sensor operation in either potentiometric or amperometric mode, as appropriate. In potentiometric mode, which measures voltage differences between working and reference electrodes in different gases, the voltage differences can be monitored with a voltmeter; however, the sensor itself does not need a power source. In room-temperature testing, the sensor achieved repeatable responses to 21 percent oxygen in nitrogen (using nitrogen as a baseline gas), and also detected oxygen from 7 to 21 percent, making Glenn's breakthrough technology usable for personal health monitoring as well as fire detection, fuel-leak detection, and environmental monitoring.

This NASA Glenn innovation is a novel multi-junction photovoltaic cell constructed using selenium as a bonding material sandwiched between a thin film multi-junction wafer and a silicon substrate wafer, enabling higher efficiencies. A multi-junction photovoltaic cell differs from a single junction cell in that it has multiple sub-cells (p-n junctions) and can convert more of the sun's energy into electricity as the light passes through each layer. To further improve the efficiencies, this cell has three junctions, where the top wafer is made from high solar energy absorbing materials that form a two-junction cell made from the III-V semiconductor family, and the bottom substrate remains as a simple silicon wafer. The selenium interlayer is applied between the top and bottom wafers, then pressure annealed at 221°C (the melting temperature of selenium), then cooled. The selenium interlayer acts as a connective layer between the top cell that absorbs the short-wavelength light and the bottom silicon-based cell that absorbs the longer wavelengths. The three-junction solar cell manufactured using selenium as the transparent interlayer has a higher efficiency, converting more than twice the energy into electricity than traditional cells. To obtain even higher efficiencies of over 40%, both the top and bottom layers can be multi-junction solar cells with the selenium layer sandwiched in between. The resultant high performance multi-junction photovoltaic cell with the selenium interlayer provides more power per unit area while utilizing a low-cost silicon-based substrate. This unprecedented combination of increased efficiency and cost savings has considerable commercial potential. This is an early-stage technology requiring additional development. Glenn welcomes co-development opportunities.

The SiOx Coated Aluminized Polyimide Film Radiator Coating uses all the exposed surfaces on the six sides of a CubeSat as radiators. All the internal components are thermally coupled to the radiators. Waste heat from the internal components is transferred by conduction to the radiators through its aluminum structure or frame. SiOx thin film coated aluminized polyimide film is used as the radiator coating. Its total thickness is approximately 0.05 mm, which is predominately the polyimide film thickness. Polyimide film is known commercially as Kapton. The coating is bonded to the CubeSat exterior by using an acrylic transfer adhesive. SiOx Coated Aluminized Polyimide Film Radiator Coatings absorptance and emittance can be tailored to meet the component thermal requirements by altering the SiOx thickness. Since the SiOx is a thin film, altering its thickness has no significant effect on the total thickness of the radiator coating. An indium tin oxide (ITO) thin film can be added to make the coating conductive, if needed, without affecting the absorptance or emittance. This coating, with or without ITO, can be used for various CubeSat applications. By tailoring the absorptance and emittance of this coating, external MLI blankets and active heater control are eliminated. The thermal connection between heat generating components and the battery eliminates the need for a battery heater.

Glenn's breakthrough technology introduces batch-fabricated, miniature sensors embedded and distributed over a large surface area of a material or product during the manufacturing process. The sensors can be utilized for test instrumentation or as an integrated in-situ monitoring system. This integrated manufacturing approach preserves the structural and mechanical system integrity by eliminating the antiquated plug-in approach, invasive machining, manual insertion, and gluing processes currently required to implant sensors into a material. The sensor ladder network of resistors and capacitors breaks down as result of the thermo-physical effects caused by temperature, shock, radiation, corrosion, or other reactions, causing a change in the electrical properties. A processor interprets these changes in the electrical properties and generates a high-resolution, large-area surface profile. The profile demonstrates the amount or rate of material deterioration and temperature change, and is used to optimize geometric structural design, develop materials, predict performance, and make decisions. These sensors play an important role as industries work to realize material performance and product design. This type of monitoring is ideal for infrastructures, nuclear enclosures, or any system susceptible to surface deterioration.